Year 13 · AQA & OCR A

Entropy & Gibbs free energy

Practise the calculations that usually cost marks: products minus reactants for ΔS°, matching J with kJ in ΔG = ΔH − TΔS, and deciding what the sign of ΔG actually tells you.

Work out what the data are asking for

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For ΔS°, keep every coefficient

Multiply each standard molar entropy by its coefficient in the balanced equation, add the products, then subtract the reactants.

ΔS° = ΣS°(products) − ΣS°(reactants)

Before you calculate ΔG

ΔH is usually in kJ mol−1. ΔS is usually in J K−1 mol−1. Divide ΔS by 1000 before using it with ΔH in kJ mol−1.

ΔG = ΔH − TΔS

Negative ΔG means thermodynamically feasible

A negative ΔG predicts that the forward change is thermodynamically feasible at the stated temperature. ΔG = 0 is the boundary. A positive ΔG means the forward change is not thermodynamically feasible under those conditions.

OCR A: feasibility does not tell you the rate. A reaction with a negative ΔG can still be extremely slow if its activation energy is large.

Use temperature to see when feasibility changes

Use the ΔG against T lab to see why some reactions become feasible only above or below a crossover temperature.

Open temperature & feasibility